Overcoming the chelate effect: hypodentate coordination of common multidentate amine ligands

被引：34

作者：

Blackman, AG ^{[1
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

来源：

COMPTES RENDUS CHIMIE | 2005年 / 8卷 / 02期

关键词：

hypodentate; transition-metal complex; amine ligand;

D O I：

10.1016/j.crci.2004.09.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The concept of hypodentate coordination, in which a multidentate ligand binds to a transition metal using fewer than the maximum number of donor atoms, is briefly reviewed, with particular reference to common aliphatic, alicyclic and aromatic amine ligands. To cite this article: A.G. Blackman, C R. Chimie 8 (2004). (C) 2004 Academie des sciences. Published by Elsevier SAS. All rights reserved.

引用

页码：107 / 119

页数：13

共 85 条

[1] 2,2'/6',2''-TERPYRIDINE (TERPY) ACTING AS A FLUXIONAL BIDENTATE LIGAND .1. TRIMETHYLPLATINUM(IV) HALIDE-COMPLEXES [PTXME3(TERPY)] (X = CL, BR OR I) - NUCLEAR-MAGNETIC-RESONANCE STUDIES OF THEIR SOLUTION DYNAMICS AND CRYSTAL-STRUCTURE OF [PTIME3(TERPY)]
ABEL, EW
DIMITROV, VS
LONG, NJ
ORRELL, KG
OSBORNE, AG
SIK, V
HURSTHOUSE, MB
MAZID, MA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (02): : 291 - 298
[2] 2,2' - 6',2''-TERPYRIDINE (TERPY) ACTING AS A FLUXIONAL BIDENTATE LIGAND .2. RHENIUM CARBONYL HALIDE-COMPLEXES, FAC-[REX(CO)3(TERPY)] (X = CL, BR OR I) - NMR-STUDIES OF THEIR SOLUTION DYNAMICS, SYNTHESIS OF CIS-[REBR(CO)2(TERPY)] AND THE CRYSTAL-STRUCTURE OF [REBR(CO)3(TERPY)]
ABEL, EW
DIMITROV, VS
LONG, NJ
ORRELL, KG
OSBORNE, AG
PAIN, HM
SIK, V
HURSTHOUSE, MB
MAZID, MA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04): : 597 - 603
[3] 2,2'6',2''-TERPYRIDINE (TERPY) ACTING AS A FLUXIONAL BIDENTATE LIGAND .4. CIS-[M(C6F5)(2)(TERPY)] (M=PD OR PT) - NUCLEAR-MAGNETIC-RESONANCE STUDIES OF THEIR SOLUTION DYNAMICS AND CRYSTAL-STRUCTURE OF CIS-[PD(C6F5)(2)(TERPY)]
ABEL, EW
ORRELL, KG
OSBORNE, AG
PAIN, HM
SIK, V
HURSTHOUSE, MB
MALIK, KMA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (23): : 3441 - 3449
[4] A MONODENTATE ETHYLENEDIAMINE COMPLEX OF COBALT(III)
ALEXANDER, MD
SPILLERT, CA
[J]. INORGANIC CHEMISTRY, 1970, 9 (10) : 2344 - +
[5] AMBIDENTATE COORDINATION OF THE TRIPYRIDYL LIGANDS 2,2'-6',2'-TERPYRIDYL, TRIS(2-PYRIDYL)-AMINE, TRIS(2-PYRIDYL)METHANE AND TRIS(2-PYRIDYL)PHOSPHINE TO CARBONYLRHENIUM CENTERS - STRUCTURAL AND SPECTROSCOPIC STUDIES
ANDERSON, PA
KEENE, FR
HORN, E
TIEKINK, ERT
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 1990, 4 (05) : 523 - 533
[6] [Cr(bipy)(C2O4)(2)](-) - A versatile building block for the design of heteropolymetallic systems .2. Syntheses and crystal structures of CuCr2(bipy)(2)(mu-C2O4)(2)(C2O4)(2)(H2O)(2)center dot 1(1)/2H2O and (AgCr(bipy)(mu-C2O4)(2)(H2O)(2))(2) and magnetic properties of the copper(II) derivative
Andruh, M
Melanson, R
Stager, CV
Rochon, FD
[J]. INORGANICA CHIMICA ACTA, 1996, 251 (1-2) : 309 - 317
[7] [Anonymous], 2003, CAMBRIDGE STRUCTURAL
[8] ARZOUMANIAN H, 1992, NEW J CHEM, V16, P965
[9] PREPARATION AND CHARACTERIZATION OF NITROSYLRUTHENIUM(III) COMPLEXES CONTAINING DIETHYLENETRIAMINE
ASANUMA, R
TOMIZAWA, H
URUSHIYAMA, A
MIKI, E
MIZUMACHI, K
ISHIMORI, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (05) : 1274 - 1282
[10] NICKEL(II) COMPLEXES OF [3K]ANENK POLYAZACYCLOALKANES (K = 7-12) - SOLUTION AND SOLID-STATE STUDIES
BENCINI, A
BIANCHI, A
CASTELLO, M
DAPPORTO, P
FAUS, J
GARCIAESPANA, E
MICHELONI, M
PAOLETTI, P
PAOLI, P
[J]. INORGANIC CHEMISTRY, 1989, 28 (16) : 3175 - 3181

← 1 2 3 4 5 6 7 8 9 →