Overcoming the chelate effect: hypodentate coordination of common multidentate amine ligands

被引:34
作者
Blackman, AG [1 ]
机构
[1] Univ Otago, Dept Chem, Dunedin, New Zealand
关键词
hypodentate; transition-metal complex; amine ligand;
D O I
10.1016/j.crci.2004.09.002
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The concept of hypodentate coordination, in which a multidentate ligand binds to a transition metal using fewer than the maximum number of donor atoms, is briefly reviewed, with particular reference to common aliphatic, alicyclic and aromatic amine ligands. To cite this article: A.G. Blackman, C R. Chimie 8 (2004). (C) 2004 Academie des sciences. Published by Elsevier SAS. All rights reserved.
引用
收藏
页码:107 / 119
页数:13
相关论文
共 85 条
  • [71] Riou-Cavellec M, 1999, CR ACAD SCI II C, V2, P147
  • [72] Syntheses and crystal structures of ruthenium complexes of 1,4,8,11-tetraazacyclotetradecane, tris(2-aminoethyl)amine (tren), and bis(2-aminoethyl)(iminomethyl)amine. A microporous layered structure consisting of {[K(tren)](2)[RuCl6]}(n-)(n) and{(H5O2)4[RuCl6]}(n+)(n)
    Sakai, K
    Yamada, Y
    Tsubomura, T
    [J]. INORGANIC CHEMISTRY, 1996, 35 (11) : 3163 - 3172
  • [73] DIE AQUOTISIERUNG VON [CREN3]3+ IN WASSRIGER PERCHLORSAURER LOSUNG
    SCHLAFER, HL
    KLING, O
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1958, 8 : 320 - 331
  • [74] Toward a hexagonal grid polymer: Synthesis, coupling, and chemically reversible surface-pinning of the star connectors, 1,3,5-C6H3(CB10H10CX)(3)
    Schoberl, U
    Magnera, TF
    Harrison, RM
    Fleischer, F
    Pflug, JL
    Schwab, PFH
    Meng, XS
    Lipiak, D
    Noll, BC
    Allured, VS
    Rudalevige, T
    Lee, S
    Michl, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (17) : 3907 - 3917
  • [75] SHINOHARA N, 2000, NEW TECHNOLOGIES MED, V1, P754
  • [76] N,N,N′,N′-tetrakis(2-pyridylmethyl)ethylenediamine and its analogues as hypodentate ligands.: Synthesis and characterization of the rhodium(III), ruthenium(II), and palladium(II) complexes
    Sokolov, M
    Umakoshi, K
    Sasaki, Y
    [J]. INORGANIC CHEMISTRY, 2002, 41 (24) : 6237 - 6243
  • [77] Ruthenium terpyridine complexes with mono- and bi-dentate dithiolene ligands
    Sugimoto, H
    Tsuge, K
    Tanaka, K
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (01): : 57 - 63
  • [78] STABLE MONODENTATE 2,2'-BIPYRIDINE COMPLEX OF IRIDIUM(III) - MODEL FOR REACTIVE INTERMEDIATES IN LIGAND DISPLACEMENT-REACTIONS OF TRIS-2,2'-BIPYRIDINE METAL-COMPLEXES
    WATTS, RJ
    HARRINGTON, JS
    VANHOUTEN, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) : 2179 - 2187
  • [79] Three-dimensional open-framework nickel aluminophosphate [NiAlP2O8][C2N2H9]:: Assembly of one-dimensional AlP2O83- chains through [NiO5N] octahedra
    Wei, B
    Yu, JH
    Shi, Z
    Qiu, SL
    Yan, WF
    Terasaki, O
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (08) : 2065 - 2067
  • [80] WERNER A, 1967, CHYMIA, V12, P221