Base promoted preparation of alkenylsilanols from allylsilanes

被引：15

作者：

Akiyama, T

Imazeki, S

机构：

[1] Department of Chemistry, Faculty of Science, Gakushuin University, Tokyo 171, 1-5-1, Mejiro, Toshima-ku

来源：

CHEMISTRY LETTERS | 1997年 / 10期

关键词：

D O I：

10.1246/cl.1997.1077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On treatment of allyl-t-butyldiphenylsilane with t-BuOK and 18-Crown-6 in DMSO at room temperature, isomerization of the olefinic double bond and subsequent substitution of phenyl group with hydroxy group took place smoothly to afford alkenylsilanol derivatives in good yields.

引用

收藏

页码：1077 / 1078

页数：2

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