The systematic generation of monodentate bridging ethanoates in dinuclear nickel(II) complexes of asymmetric compartmental ligands

被引：32

作者：

Adams, H ^{[1
]}

Clunas, S ^{[1
]}

Fenton, DE ^{[1
]}

Spey, SE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 03期

关键词：

Binding energy - Chelation - Chemical analysis - Chemical bonds - Column chromatography - Infrared spectroscopy - Molecular structure - Solvents;

D O I：

10.1039/b107928j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The presence of five-membered chelating rings derived from the iminic and aminic pendant arms in dinuclear nickel(II) complexes of asymmetric compartmental ligands gives rise to syn-syn bidentate ethanoate bridging in these complexes whereas the introduction of a six-membered chelating ring at the iminic binding site induces an ethanoate shift generating a monodentate bridging ethanoate group.

引用

页码：441 / 448

页数：8

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