Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media

被引:153
作者
Ley, SV
Ramarao, C
Gordon, RS
Holmes, AB
Morrison, AJ
McConvey, IF
Shirley, IM
Smith, SC
Smith, MD
机构
[1] Univ Chem Labs, Cambridge CB2 1EW, England
[2] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 3RA, England
[3] AstraZeneca Proc Res & Dev, Macclesfield SK10 2NA, Cheshire, England
[4] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England
关键词
D O I
10.1039/b200677b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladium(II) acetate microencapsulated in polyurea (MC-[Pd]) is an economical and versatile heterogeneous catalyst for a range of phosphine-free cross-coupling reactions in both conventional solvents and supercritical carbon dioxide (scCO(2)); the catalyst can be recovered by a simple filtration and recycled up to four times.
引用
收藏
页码:1134 / 1135
页数:2
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