Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide

被引:48
作者
Early, TR
Gordon, RS
Carroll, MA
Holmes, AB
Shute, RE
McConvey, IF
机构
[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 3RA, England
[2] Astrazeneca Res & Dev, Macclesfield SK10 4TG, Cheshire, England
[3] Astrazeneca Proc Res & Dev, Macclesfield SK10 4TG, Cheshire, England
关键词
D O I
10.1039/b106808c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Heck and Suzuki reactions proceed in good yield in supercritical carbon dioxide in the presence of palladium acetate and tri-tert-butylphosphine with both free and polymer-tethered substrates.
引用
收藏
页码:1966 / 1967
页数:2
相关论文
共 20 条
[1]  
[Anonymous], 1999, CHEM SYNTHESIS USING
[2]   Hydroformylation of hex-1-ene in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes [J].
Bach, I ;
Cole-Hamilton, DJ .
CHEMICAL COMMUNICATIONS, 1998, (14) :1463-1464
[3]   The heck reaction as a sharpening stone of palladium catalysis [J].
Beletskaya, IP ;
Cheprakov, AV .
CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066
[4]   Heck reactions using water-soluble metal complexes in supercritical carbon dioxide [J].
Bhanage, BM ;
Ikushima, Y ;
Shirai, M ;
Arai, M .
TETRAHEDRON LETTERS, 1999, 40 (35) :6427-6430
[5]   Palladium-catalysed carbon-carbon bond formation in supercritical carbon dioxide [J].
Carroll, MA ;
Holmes, AB .
CHEMICAL COMMUNICATIONS, 1998, (13) :1395-1396
[6]   Polymer synthesis and processing using supercritical carbon dioxide [J].
Cooper, AI .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (02) :207-234
[7]   New directions in inorganic and metal-organic coordination chemistry in supercritical fluids [J].
Darr, JA ;
Poliakoff, M .
CHEMICAL REVIEWS, 1999, 99 (02) :495-541
[8]  
EARLY TR, UNPUB
[9]   The Suzuki, the Heck, and the Stille reaction -: three versatile methods for the introduction of new C-C bonds on solid support [J].
Franzén, R .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2000, 78 (07) :957-962
[10]   On the efficiency of tetraalkylammonium salts in Heck type reactions [J].
Jeffery, T .
TETRAHEDRON, 1996, 52 (30) :10113-10130