The Synthesis of Nanostructured Ni5P4 Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting

被引：811

作者：

Ledendecker, Marc ^{[1
]}

Calderon, Sandra Krick ^{[2
]}

Papp, Christian ^{[2
]}

Steinrueck, Hans-Peter ^{[2
]}

Antonietti, Markus ^{[1
]}

Shalom, Menny ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany

[2] Univ Erlangen Nurnberg, Dept Phys Chem 2, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 42期

关键词：

ceramics; hydrogen evolution reaction; nickel phosphides; oxygen evolution reaction; water splitting reaction; HYDROGEN-EVOLUTION; CORROSION-RESISTANCE; NICKEL PHOSPHIDE; THIN-FILM; EFFICIENT; NANOPARTICLES; ELECTROLYSIS; CATALYSTS; CARBON; ELECTRODES;

D O I：

10.1002/anie.201502438

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The investigation of nickel phosphide (Ni5P4) as a catalyst for the hydrogen (HER) and oxygen evolution reaction (OER) in strong acidic and alkaline environment is described. The catalyst can be grown in a 3D hierarchical structure directly on a nickel substrate, thus making it an ideal candidate for practical water splitting devices. The activity of the catalyst towards the HER, together with its high stability especially in acidic solution, makes it one of the best non-noble materials described to date. Furthermore, Ni5P4 was investigated in the OER and showed activity superior to pristine nickel or platinum. The practical relevance of Ni5P4 as a bifunctional catalyst for the overall water splitting reaction was demonstrated, with 10 mA cm(-2) achieved below 1.7 V.

引用

页码：12361 / 12365

页数：5

共 51 条

[1]

[Anonymous], 2015, ANGEW CHEM INT EDIT

[2] Specificity of the kinetics of H2, evolution to the structure of single-crystal Pt surfaces, and the relation between opd and upd H [J].

Barber, J ;

Morin, S ;

Conway, BE .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 446 (1-2) :125-138

[3] The influence of surface finishing on the electrocatalytic properties of nickel for the oxygen evolution reaction (OER) in alkaline solution [J].

Bocca, C ;

Barbucci, A ;

Cerisola, G .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1998, 23 (04) :247-252

[4] Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production [J].

Chen, W. -F. ;

Wang, C. -H. ;

Sasaki, K. ;

Marinkovic, N. ;

Xu, W. ;

Muckerman, J. T. ;

Zhu, Y. ;

Adzic, R. R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (03) :943-951

[5] Electrochemical hydrogen production from water electrolysis using ionic liquid as electrolytes:: Towards the best device [J].

de Souza, Roberto F. ;

Padilha, Janine C. ;

Goncalves, Reinaldo S. ;

de Souza, Michele O. ;

Rault-Berthelot, Joelle .

JOURNAL OF POWER SOURCES, 2007, 164 (02) :792-798

[6] Structural modifications and electrochemical behaviour of the β(II)-Ni(OH)2/β(III)-NiOOH redox couple upon galvanostatic charging/discharging cycling [J].

Deabate, S ;

Henn, F .

ELECTROCHIMICA ACTA, 2005, 50 (14) :2823-2835

[7] Hydrogen futures: toward a sustainable energy system [J].

Dunn, S .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (03) :235-264

[8] Electroless deposited Ni-P alloys: corrosion resistance mechanism [J].

Elsener, Bernhard ;

Crobu, Maura ;

Scorciapino, Mariano Andrea ;

Rossi, Antonella .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2008, 38 (07) :1053-1060

[9] Earth-Abundant Cobalt Pyrite (CoS2) Thin Film on Glass as a Robust, High-Performance Counter Electrode for Quantum Dot-Sensitized Solar Cells [J].

Faber, Matthew S. ;

Park, Kwangsuk ;

Caban-Acevedo, Miguel ;

Santra, Pralay K. ;

Jin, Song .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (11) :1843-1849

[10] Easily-prepared dinickel phosphide (Ni2P) nanoparticles as an efficient and robust electrocatalyst for hydrogen evolution [J].

Feng, Ligang ;

Vrubel, Heron ;

Bensimon, Michael ;

Hu, Xile .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (13) :5917-5921

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