Synthesis and characterization of two new cadmium phosphonocarboxylates Cd2(OH)(O3PC2H4CO2) and Cd3(O3PC2H4CO2)2•2H2O

被引：65

作者：

Fredoueil, F

Evain, M

Massiot, D

Bujoli-Doeuff, M

Janvier, P

Clearfield, A

Bujoli, B

机构：

[1] Organ Synth Lab, CNRS, UMR 6513, F-44322 Nantes 03, France

[2] Inst Mat Jean Rouxel, CNRS, UMR 6502, F-44322 Nantes 03, France

[3] CRMHT UPR CNRS 4212, F-45071 Orleans 02, France

[4] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b110275n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of 2-carboxyethylphosphonic acid with cadmium salts is described, leading to two new pillared layered phosphonates that were fully characterized using P-31 and Cd-113 solid state NMR spectroscopy. A densely packed arrangement is observed for Cd-2(OH)(O3PCH4CO2), exhibiting structural features uncommon in metal phosphonates: a triply bridging OH, a (222) connectivity for the PO3 groups and a mixed 5-fold and 6-fold coordination for the metal.

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页码：1508 / 1512

页数：5

相关论文

共 40 条

[1] Relationship between solid state NMR parameters and X-ray structural data in tricadmium phosphates [J].

Aime, S ;

Digilio, G ;

Gobetto, R ;

Bigi, A ;

Ripamonti, A ;

Roveri, N ;

Gazzano, M .

INORGANIC CHEMISTRY, 1996, 35 (01) :149-154

[2]

BENITEZ IO, 2002, J AM CHEM SOC

[3] Molecular design of intercalation based sensors .2. Sensing of carbon dioxide in functionalized thin films of copper octanediylbis(phosphonate) [J].

Brousseau, LC ;

Aurentz, DJ ;

Benesi, AJ ;

Mallouk, TE .

ANALYTICAL CHEMISTRY, 1997, 69 (04) :688-694

[4] Molecular design of intercalation based sensors .1. Ammonia sensing with quartz crystal microbalances modified by copper biphenylbis(phosphonate) thin films [J].

Brousseau, LC ;

Mallouk, TE .

ANALYTICAL CHEMISTRY, 1997, 69 (04) :679-687

[5] FORMATION OF QUANTUM-SIZE SEMICONDUCTOR PARTICLES IN A LAYERED METAL PHOSPHONATE HOST LATTICE [J].

CAO, G ;

RABENBERG, LK ;

NUNN, CM ;

MALLOUK, TE .

CHEMISTRY OF MATERIALS, 1991, 3 (01) :149-156

[6] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND INTERCALATION CHEMISTRY OF 2 LAYERED CADMIUM ORGANOPHOSPHONATES [J].

CAO, G ;

LYNCH, VM ;

YACULLO, LN .

CHEMISTRY OF MATERIALS, 1993, 5 (07) :1000-1006

[7]

Clearfield A, 1998, PROG INORG CHEM, V47, P371

[8] Shape selectivity for alkane hydroxylation with a new class of phosphonate-based heterogenised manganese porphyrins [J].

Deniaud, D ;

Spyroulias, GA ;

Bartoli, JF ;

Battioni, P ;

Mansuy, D ;

Pinel, C ;

Odobel, F ;

Bujoli, B .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (08) :901-905

[9] SYNTHESIS AND CATALYTIC PROPERTIES OF MANGANESE PORPHYRINS INCORPORATED INTO PHOSPHONATE NETWORKS [J].

DENIAUD, D ;

SCHOLLHORN, B ;

MANSUY, D ;

ROUXEL, J ;

BATTIONI, P ;

BUJOLI, B .

CHEMISTRY OF MATERIALS, 1995, 7 (05) :995-1000

[10] Synthesis and characterization of Co3(O2CCH2CH2PO3)2•6H2O, a metal carboxylate-phosphonate with a framework structure [J].

Distler, A ;

Sevov, SC .

CHEMICAL COMMUNICATIONS, 1998, (09) :959-960

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