Shape selectivity for alkane hydroxylation with a new class of phosphonate-based heterogenised manganese porphyrins

被引：34

作者：

Deniaud, D

Spyroulias, GA

Bartoli, JF

Battioni, P

Mansuy, D

Pinel, C

Odobel, F

Bujoli, B

机构：

[1] Synth Organ Lab, CNRS, UMR 6513, F-44322 Nantes 03, France

[2] Univ Paris 05, Chim & Biochim Pharmacol & Toxicol Lab, CNRS, URA 400, F-75270 Paris, France

[3] Inst Rech Catalyse, CNRS, UPR 5401, F-69626 Villeurbanne, France

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 08期

关键词：

D O I：

10.1039/a709254g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four new manganese(III) porphyrins, heterogenised as insoluble zinc phosphonates, exhibit behaviour markedly different from their homogeneous counterparts in the competitive hydroxylation of alkane mixtures (i.e., cyclododecane-cyclohexane), using iodosylbenzene as the oxidant. The cyclohexanol : cyclododecanol ratio can be increased by as much as five, owing to shape selectivity effects imposed by the phosphonate support.

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页码：901 / 905

页数：5

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