Metalloporphyrinosilicas: A new class of hybrid organic-inorganic materials acting as selective biomimetic oxidation catalysts

被引：95

作者：

Battioni, P ^{[1
]}

Cardin, E ^{[1
]}

Louloudi, M ^{[1
]}

Schollhorn, B ^{[1
]}

Spyroulias, GA ^{[1
]}

Mansuy, D ^{[1
]}

Traylor, TG ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM 0358,LA JOLLA,CA 92093

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New hybrid organic-inorganic materials are prepared by hydrolysis and polycondensation, or cocondensation with tetraethoxysilane, of iron porphyrins bearing a trifluorosilyl function; despite their insolubility, these 'metalloporphyrinosilicas' are efficient catalysts for alkene epoxidation by PhIO or Bu(t)OOH and alkane hydroxylation by PhIO, the iron porphyrinosilicas with low specific surface areas (approximate to 60 m(2) g(-1)) catalysing a shape-selective hydroxylation of alkane mixtures.

引用

页码：2037 / 2038

页数：2

共 18 条

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