AN EASY ACCESS TO POLYHALOGENATED METALLOPORPHYRINS COVALENTLY BOUND TO POLYMERIC SUPPORTS AS EFFICIENT CATALYSTS FOR HYDROCARBON OXIDATION

被引：84

作者：

BATTIONI, P ^{[1
]}

BARTOLI, JF ^{[1
]}

MANSUY, D ^{[1
]}

BYUN, YS ^{[1
]}

TRAYLOR, TG ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM,LA JOLLA,CA 92110

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期

关键词：

D O I：

10.1039/c39920001051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of silica, montmorillonite and polystyrene bearing amino functions with several polyhalogenated metalloporphyrins gave an easy one-step access to new supported catalysts, owing to a selective nucleophilic substitution of the para-halogen atoms of the porphyrin meso-aryl groups by the polymer amine function; these catalysts were very active for cyclooctene epoxidation and alkane hydroxylation by PhlO.

引用

页码：1051 / 1053

页数：3

共 19 条

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