Boron-Capped Tris(glyoximato) Cobalt Clathrochelate as a Precursor for the Electrodeposition of Nanoparticles Catalyzing H2 Evolution in Water

被引：166

作者：

Anxolabehere-Mallart, Elodie ^{[1
]}

Costentin, Cyrille ^{[1
]}

Fournier, Maxime ^{[1
]}

Nowak, Sophie ^{[2
]}

Robert, Marc ^{[1
]}

Saveant, Jean-Michel ^{[1
]}

机构：

[1] Univ Paris Diderot, CNRS, UMR 7591, Electrochim Mol Lab, F-75205 Paris 13, France

[2] Univ Paris Diderot, UFR Chim, F-75205 Paris 13, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 14期

关键词：

ELECTROCATALYTIC HYDROGEN EVOLUTION; GENERATING HYDROGEN; FUNCTIONAL MODELS; CATALYSIS; COMPLEXES; COBALOXIMES;

D O I：

10.1021/ja301134e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical investigation of a boron-capped tris(glyoximato)cobalt clathrochelate complex in the presence of acid reveals that the catalytic activity toward hydrogen evolution results from an electro-deposition of cobalt-containing nanoparticles on the electrode surface at a modest cathodic potential. The deposited particles act as remarkably active catalysts for H-2 production in water at pH 7.

引用

页码：6104 / 6107

页数：4

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