Small molecule mimics of hydrogenases: hydrides and redox

被引：581

作者：

Gloaguen, Frederic ^{[1
]}

Rauchfuss, Thomas B. ^{[2
]}

机构：

[1] Univ Bretagne Occidentale, CNRS, UMR 6521, CS 93837, F-29238 Brest 3, France

[2] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 01期

关键词：

ELECTROCHEMICAL PROTON REDUCTION; ACTIVE-SITE MODELS; FE-FE HYDROGENASE; BRIDGING CARBONYL; ELECTRON-TRANSFER; ONLY HYDROGENASE; TERMINAL HYDRIDE; MIXED-VALENT; IRON; COMPLEXES;

D O I：

10.1039/b801796b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review is aimed at chemical scientists interested in understanding and exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features are analyzed for the active sites of the two most important hydrogenases. Reactivity is emphasized, focusing on mechanism and catalysis. Through this analysis, gaps are identified in the synthesis of functional replicas of these fascinating and potentially useful enzymes.

引用

页码：100 / 108

页数：9

共 69 条

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