On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

被引：57

作者：

Best, Stephen P. ^{[1
]}

Borg, Stacey J.

White, Jonathan M.

Razavet, Mathieu

Pickett, Christopher J.

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic, Australia

[2] Univ E Anglia, Sch Chem & Pharm, Norwich NR4 7TJ, Norfolk, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 42期

关键词：

D O I：

10.1039/b712758h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that a dinuclear assembly apparently providing the first example of a synthetic molecule exhibiting key features of the diiron subsite of [FeFe] hydrogenase, viz. CO-bridging of a coordinatively unsaturated, dithiolate- bridged mixed-valence diiron centre, is in fact a diamagnetic tetranuclear complex.

引用

页码：4348 / 4350

页数：3

共 22 条

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