Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation

被引：36

作者：

Andrews, Michael B. ^{[1
]}

Cahill, Christopher L. ^{[1
]}

机构：

[1] George Washington Univ, Dept Chem, Washington, DC 20052 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 27期

关键词：

crystal engineering; ligand design; phase transitions; uranium; X-ray diffraction; ORGANIC FRAMEWORKS; ROOM-TEMPERATURE; COMPLEXATION; CONSTRUCTION; HYDROLYSIS; METAL;

D O I：

10.1002/anie.201202402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phase to phase: The in situ hydrolysis of 4-(bromomethyl)benzoic acid to 4-(hydroxymethyl)benzoic acid (HMBA) in the presence of the uranyl cation has resulted in the novel hybrid material (A)[UO 2(HMBA) 3] (A=NH 4 + or H 3O +), which was characterized by X-ray diffraction. On exposure to ethanol the material undergoes a solid-state phase transformation, accompanied by the loss of a ligand and counterion to form [UO 2(HMBA) 2] (see scheme; O red, C black). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6631 / 6634

页数：4

共 20 条

[1] In situ ligand synthesis and construction of an unprecedented three-dimensional array with silver(I): a new approach to inorganic crystal engineering [J].

Blake, AJ ;

Champness, NR ;

Chung, SSM ;

Li, WS ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1997, (17) :1675-1676

[2] Study of uranyl(VI) malonate complexation by time resolved laser-induced fluorescence spectroscopy (TRLFS) [J].

Brachmann, A ;

Geipel, G ;

Bernhard, G ;

Nitsche, H .

RADIOCHIMICA ACTA, 2002, 90 (03) :147-153

[3] Homo- and heterometallic coordination polymers from the f elements [J].

Cahill, Christopher L. ;

de Lill, Daniel T. ;

Frisch, Mark .

CRYSTENGCOMM, 2007, 9 (01) :15-26

[4]

Chen C. L., 2005, ANGEW CHEM, V117, P6831

[5] [Co2(ppca)2(H2O)(V4O12)0.5]:: A framework material exhibiting reversible shrinkage and expansion through a single-crystal-to-single-crystal transformation involving a change in the cobalt coordination environment [J].

Chen, CL ;

Goforth, AM ;

Smith, MD ;

Su, CY ;

zur Loye, HC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (41) :6673-6677

[6] Solvent effect on the construction of two microporous yttrium-organic frameworks with high thermostability via in situ ligand hydrolysis [J].

Dong, Bao-Xia ;

Gu, Xiao-Jun ;

Xu, Qiang .

DALTON TRANSACTIONS, 2010, 39 (24) :5683-5687

[7] Metal-mediated one-step in situ oxidation of 2,9-dimethyl-1,10-phenanthroline and formation of transition-metal and lanthanoid complexes [J].

Fan, Lin-Lin ;

Li, Cui-Jin ;

Meng, Zhao-Sha ;

Tong, Ming-Liang .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (25) :3905-3909

[8] (6,3)-honeycomb structures of Uranium(VI) benzenedicarboxylate derivatives: The use of noncovalent interactions to prevent interpenetration [J].

Go, Yong Bok ;

Wang, Xiqu ;

Jacobson, Allan J. .

INORGANIC CHEMISTRY, 2007, 46 (16) :6594-6600

[9] Solid-state water-catalyzed transformation at room temperature of a nonluminescent linear-chain uranyl phenylphosphonate into a luminescent one [J].

Grohol, D ;

Clearfield, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (20) :4662-4668

[10] PREDICTION OF DENSITY IN ORGANIC-CRYSTALS [J].

IMMIRZI, A ;

PERINI, B .

ACTA CRYSTALLOGRAPHICA SECTION A, 1977, 33 (JAN1) :216-218

← 1 2 →