In situ ligand synthesis and construction of an unprecedented three-dimensional array with silver(I): a new approach to inorganic crystal engineering

被引:230
作者
Blake, AJ [1 ]
Champness, NR [1 ]
Chung, SSM [1 ]
Li, WS [1 ]
Schroder, M [1 ]
机构
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
关键词
D O I
10.1039/a702972a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of 1,2-trans-(4-pyridyl)ethene with AgBF4 results in the formation of a three-dimensional network based upon a cyclobutane-linked tetrapyridyl ligand, 1,2,3,4-tetrakis(4-pyridyl)cyclobutane, linked by Ag-I ions; the in situ formation of the ligand represents a potential new direction for inorganic crystal engineering.
引用
收藏
页码:1675 / 1676
页数:2
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