Crystal engineering: The effects of pi-pi interactions in copper(I) and silver(I) complexes of 2,7-diazapyrene

被引：145

作者：

Blake, AJ

Champness, NR

Khlobystov, AN

Lemenovskii, DA

Li, WS

Schroder, M

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

[2] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,RUSSIA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 15期

关键词：

D O I：

10.1039/a702050c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu-I and Ag-I ions: {[(CuL2)-L-I]PF6}(infinity) shows an adamantoid network with three interpenetrating networks, while {[(AgL2)-L-I(MeCN)(2)]BF4}(infinity) forms linear chains of [AgL](infinity) units linked by apparent pi-pi stacking and Ag ... Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.

引用

页码：1339 / 1340

页数：2

共 21 条

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