Control of interpenetrating copper(I) adamantoid networks: Synthesis and structure of {[Cu(bpe)(2)]BF4}(n)

被引:226
作者
Blake, AJ [1 ]
Champness, NR [1 ]
Chung, SSM [1 ]
Li, WS [1 ]
Schroder, M [1 ]
机构
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
关键词
D O I
10.1039/a700866j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lengthening of linking bipyridyl ligands in interlocking copper(I)-heterocycle adamantoid arrays increases the volume of the adamantoid cages and consequently the number of observed interpenetrating networks: factors influencing the observed structures of these interpenetrating complexes are described in the context of the structure of {[Cu(bpe)(2)]BF4}(n)[bpe = 1,2-trans-(4-pyridyl)ethene].
引用
收藏
页码:1005 / 1006
页数:2
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