A Wellsian 'three-dimensional' racemate: Eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed

被引：126

作者：

Abrahams, BF ^{[1
]}

Batten, SR ^{[1
]}

Hamit, H ^{[1
]}

Hoskins, BF ^{[1
]}

Robson, R ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001313

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of solvated [Zn(tpt)(2/3)(SiF6)(H2O)(2)-(MeOH)I [tpt = 2,4,6-tris(4-pyridyl)-1,3,5-triazine] is comprised of eight independent [Zn-3(tpt)(2)](n) networks with the (10,3)-a topology, four of one handedness and four of the other, which interpenetrate in a remarkable way, aspects of which were postulated by A. F. Wells almost twenty years ago.

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页码：1313 / 1314

页数：2

相关论文

共 11 条

[1] 2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE AS A 5-CONNECTING BUILDING-BLOCK FOR INFINITE NETS [J].

BATTEN, SR ;

HOSKINS, BF ;

ROBSON, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :820-822

[2] 2 INTERPENETRATING 3D NETWORKS WHICH GENERATE SPACIOUS SEALED-OFF COMPARTMENTS ENCLOSING OF THE ORDER OF 20 SOLVENT MOLECULES IN THE STRUCTURES OF ZN(CN)(NO3)(TPT)(2/3)CENTER-DOT-SOLV (TPT=2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE, SOLV=SIMILAR-TO-3/4C(2)H(2)CL(4)CENTER-DOT-3/4CH(3)OH OR SIMILAR-TO-3/2CHCL(3)CENTER-DOT-1/3CH(3)OH) [J].

BATTEN, SR ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5385-5386

[3]

BATTEN SR, 1995, ANGEW CHEM, V107, P884

[4] PHOTOCHEMICAL-SYNTHESIS AND STRUCTURE OF A 3-DIMENSIONAL ANIONIC POLYMERIC NETWORK OF AN IRON(II) OXALATO COMPLEX WITH TRIS(2,2'-BIPYRIDINE)IRON(II) CATIONS [J].

DECURTINS, S ;

SCHMALLE, HW ;

SCHNEUWLY, P ;

OSWALD, HR .

INORGANIC CHEMISTRY, 1993, 32 (10) :1888-1892

[5] DIOXOPORPHYRINS AS SUPRAMOLECULAR BUILDING-BLOCKS - OLIGOMER SYNTHESIS VIA PREASSEMBLY ON A LIGAND TEMPLATE [J].

MCCALLIEN, DWJ ;

SANDERS, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (24) :6611-6612

[6]

Sheldrick G. M., 1986, SHELXS 86 PROGRAM CR

[7]

Sheldrick GM., 1993, SHELXL 93 PROGRAM CR, DOI DOI 10.1107/S2053229614026540

[8]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[9] A CONVERGENT APPROACH TO UNSYMMETRICAL PORPHYRIN OLIGOMERS [J].

VIDALFERRAN, A ;

MULLER, CM ;

SANDERS, JKM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (23) :2657-2658

[10]

Wells A.F, 1977, Three dimensional nets and polyhedra