Large scale synthesis of carbon nanofibers by catalytic decomposition of ethane on nickel nanoclusters decorating carbon nanotubes

被引:92
作者
Pham-Huu, C
Keller, N
Roddatis, VV
Mestl, G
Schlögl, R
Ledoux, MJ
机构
[1] Univ Strasbourg, Lab Mat Surfaces & Proc Catalyse, CNRS, UMR 7515, F-67087 Strasbourg 02, France
[2] Max Planck Gesell, Fritz Haber Inst, Abt Anorgan Chem, D-14195 Berlin, Germany
关键词
D O I
10.1039/b106512m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A large scale synthesis of carbon nanofibers with a controlled diameter of about 50 nm has been achieved at relatively low temperatures (550-650degreesC) by the decomposition of ethane on a carbon nanotube supported nickel catalyst. The carbon nanofibers can be used as a catalyst or a catalyst support without subsequent purification, due to the use of carbon nanotubes as support, the high nanofiber yields, and the purity obtained.
引用
收藏
页码:514 / 521
页数:8
相关论文
共 39 条
[1]   CARBON NANOTUBES AT AS-GROWN TOP SURFACE OF COLUMNAR CARBON DEPOSIT [J].
ANDO, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1993, 32 (9B) :L1342-L1345
[2]  
AYAJAN PM, 1999, CHEM MATER, V11, P3862
[3]  
Bansal R.C., 1988, ACTIVE CARBON
[4]   COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS [J].
BETHUNE, DS ;
KIANG, CH ;
DEVRIES, MS ;
GORMAN, G ;
SAVOY, R ;
VAZQUEZ, J ;
BEYERS, R .
NATURE, 1993, 363 (6430) :605-607
[5]  
Cassell AM, 1999, J PHYS CHEM B, V103, P6484, DOI 10.1021/jp990957sCCC:$18.00
[6]   Preparation of carbon nanofibers by the floating catalyst method [J].
Ci, LJ ;
Li, YH ;
Wei, BQ ;
Liang, J ;
Xu, CL ;
Wu, DH .
CARBON, 2000, 38 (14) :1933-1937
[7]   Carbon nanofibers: Catalytic synthesis and applications [J].
De Jong, KP ;
Geus, JW .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2000, 42 (04) :481-510
[8]  
deBoer J.H., 1958, STRUCTURE PROPERTIES
[9]   BUCKYTUBES AND DERIVATIVES - THEIR GROWTH AND IMPLICATIONS FOR BUCKYBALL FORMATION [J].
DRAVID, VP ;
LIN, X ;
WANG, Y ;
WANG, XK ;
YEE, A ;
KETTERSON, JB ;
CHANG, RPH .
SCIENCE, 1993, 259 (5101) :1601-1604
[10]   Optimization of catalytic production and purification of buckytubes [J].
Fonseca, A ;
Hernadi, K ;
Nagy, JB ;
Bernaerts, D ;
Lucas, AA .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 107 (1-3) :159-168