Large scale synthesis of carbon nanofibers by catalytic decomposition of ethane on nickel nanoclusters decorating carbon nanotubes

被引:92
作者
Pham-Huu, C
Keller, N
Roddatis, VV
Mestl, G
Schlögl, R
Ledoux, MJ
机构
[1] Univ Strasbourg, Lab Mat Surfaces & Proc Catalyse, CNRS, UMR 7515, F-67087 Strasbourg 02, France
[2] Max Planck Gesell, Fritz Haber Inst, Abt Anorgan Chem, D-14195 Berlin, Germany
关键词
D O I
10.1039/b106512m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A large scale synthesis of carbon nanofibers with a controlled diameter of about 50 nm has been achieved at relatively low temperatures (550-650degreesC) by the decomposition of ethane on a carbon nanotube supported nickel catalyst. The carbon nanofibers can be used as a catalyst or a catalyst support without subsequent purification, due to the use of carbon nanotubes as support, the high nanofiber yields, and the purity obtained.
引用
收藏
页码:514 / 521
页数:8
相关论文
共 39 条
[21]  
Mestl G, 2001, ANGEW CHEM INT EDIT, V40, P2066, DOI 10.1002/1521-3773(20010601)40:11<2066::AID-ANIE2066>3.0.CO
[22]  
2-I
[23]  
Mestl G., 2001, ANGEW CHEM, V113, P2122
[24]   Catalytic behavior of graphite nanofiber supported nickel particles. 2. The influence of the nanofiber structure [J].
Park, C ;
Baker, RTK .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (26) :5168-5177
[25]   Oxidative dehydrogenation of ethylbenzene on activated carbon catalysts. I. Influence of surface chemical groups [J].
Pereira, MFR ;
Orfao, JJM ;
Figueiredo, JL .
APPLIED CATALYSIS A-GENERAL, 1999, 184 (01) :153-160
[26]   Carbon nanofiber supported palladium catalyst for liquid-phase reactions - An active and selective catalyst for hydrogenation of cinnamaldehyde into hydrocinnamaldehyde [J].
Pham-Huu, C ;
Keller, N ;
Ehret, G ;
Charbonniere, LJ ;
Ziessel, R ;
Ledoux, MJ .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 170 (1-2) :155-163
[27]   Carbon nanofiber supported palladium catalyst for liquid-phase reactions.: An active and selective catalyst for hydrogenation of C=C bonds [J].
Pham-Huu, C ;
Keller, N ;
Charbonniere, LJ ;
Ziessle, R ;
Ledoux, MJ .
CHEMICAL COMMUNICATIONS, 2000, (19) :1871-1872
[28]   CATALYTIC ENGINEERING OF CARBON NANOSTRUCTURES [J].
RODRIGUEZ, NM ;
CHAMBERS, A ;
BAKER, RTK .
LANGMUIR, 1995, 11 (10) :3862-3866
[29]   A REVIEW OF CATALYTICALLY GROWN CARBON NANOFIBERS [J].
RODRIGUEZ, NM .
JOURNAL OF MATERIALS RESEARCH, 1993, 8 (12) :3233-3250
[30]  
Rylander P, 1979, CATALYTIC HYDROGENAT, P1