Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

被引：341

作者：

Dietzel, Pascal D. C. ^{[1
]}

Johnsen, Rune E. ^{[2
]}

Fjellvag, Helmer ^{[2
]}

Bordiga, Silvia ^{[3
,4
]}

Groppo, Elena ^{[3
,4
]}

Chavan, Sachin ^{[3
,4
]}

Blom, Richard ^{[1
]}

机构：

[1] SINTEF Mat & Chem, N-0314 Oslo, Norway

[2] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

[3] IFM, Dipartimento Chim, I-10125 Turin, Italy

[4] NIS Ctr Excellence, I-10125 Turin, Italy

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 41期

关键词：

D O I：

10.1039/b810574j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The microporous metal-organic framework Ni-2(dhtp) (H(4)dhtp = 2,5-dihydroxyterephthalic acid) shows distinct end-on CO2 coordination to coordinatively unsaturated nickel sites giving rise to high CO2 adsorption capacity at sub-atmospheric pressures and ambient temperatures.

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收藏

页码：5125 / 5127

页数：3

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