Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate

被引：67

作者：

Akine, Shigehisa ^{[1
]}

Matsumoto, Takashi ^{[1
]}

Nabeshima, Tatsuya ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 38期

关键词：

D O I：

10.1039/b810426c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented one-handed coiled-coil structure was formed in the crystal of a Zn(3)La tetranuclear metallohelicate, in which the handedness of both the helical component and the helical array was well controlled by the chiral auxiliary of the flexible acyclic ligand.

引用

页码：4604 / 4606

页数：3

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