Guest-dependent inversion rate of a tetranuclear single metallohelicate

被引:54
作者
Akine, Shigehisa [1 ]
Taniguchi, Takanori [1 ]
Matsumoto, Takashi [1 ]
Nabeshima, Tatsuya [1 ]
机构
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
关键词
D O I
10.1039/b610641b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexation of linear hexaoxime ligand H6L with Zn2+ and Mn+ (= La3+, Ba2+) afforded a tetranuclear single metallohelicate [LZn3M](n+), whose inversion rate can be modulated by the central metal Mn+.
引用
收藏
页码:4961 / 4963
页数:3
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