Heterometallic Zn2La and ZnLu complexes formed by site-selective transmetalation of a dimeric homotrinuclear zinc(II) complex

被引：25

作者：

Akine, Shigehisa ^{[1
]}

Taniguchi, Takanori ^{[1
]}

Nabeshima, Tatsuya ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMISTRY LETTERS | 2006年 / 35卷 / 06期

关键词：

D O I：

10.1246/cl.2006.604

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transmetalation of a dimeric homotrinuclear zinc(II) complex [(3-MeOsalamo)(2)Zn-3] with Lu3+ and La3+ afforded heterometallic dinuclear [(3-MeOsalamo)ZnLu](3+) and trinuclear [(3-MeOsalamO)(2)Zn2La](3+) complexes, respectively, whose structures were determined by X-ray crystallography. The transmetalation process was investigated by (HNMR)-H-1 titrations.

引用

页码：604 / 605

页数：2

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