Cooperative formation of trinuclear zinc(ll) complexes via complexation of a tetradentate oxime chelate ligand, salamo, and zinc(ll) acetate

被引：123

作者：

Akine, S ^{[1
]}

Taniguchi, T ^{[1
]}

Nabeshima, T ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 20期

关键词：

D O I：

10.1021/ic049282k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel trinuclear zinc(II) complexes [Zn3L2(OAc)(2)] (L = salamo, 3-MeOsalamo) were synthesized, and their structures were determined by X-ray crystallography. Ligation of methoxy groups in the salamo ligand causes a significantly different coordination mode of the central zinc atom in the trinuclear system. The complexes between the salamo ligands and zinc(II) in methanol formed exclusively and very cooperatively. In contrast to other imine ligands, the mononuclear [ZnL] and other complexes are not observed at all.

引用

页码：6142 / 6144

页数：3

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