Control of the polarity of molecular-beam-epitaxy-grown GaN thin films by the surface nitridation of Al2O3 (0001) substrates

被引:46
作者
Mikroulis, S
Georgakilas, A
Kostopoulos, A
Cimalla, V
Dimakis, E
Komninou, P
机构
[1] FORTH, Inst Elect Struct & Laser, Microelect Res Grp, Iraklion 71110, Greece
[2] Univ Crete, Dept Phys, Iraklion, Greece
[3] Aristotelian Univ Thessaloniki, Dept Phys, Solid State Sect, GR-54006 Thessaloniki, Greece
关键词
D O I
10.1063/1.1472481
中图分类号
O59 [应用物理学];
学科分类号
摘要
The nitridation of Al2O3 (0001) substrate surfaces by radio-frequency nitrogen plasma has been investigated. A 1.5-nm-thick surface nitride layer occurred for 100 min nitridation at high substrate temperature, while the nitridation appeared to be limited to a surface atomic plane at low temperature. In-plane lattice constant relaxation was observed in both cases. A high nitridation temperature resulted into a Ga face and a low temperature to N-face polarity of overgrown GaN films. However, low temperature nitridation and an AlN buffer layer also produced a Ga-face polarity. The results are consistent with low formation energy of AlN/sapphire films with Ga-face polarity. (C) 2002 American Institute of Physics.
引用
收藏
页码:2886 / 2888
页数:3
相关论文
共 14 条
[1]   Study of the correlation between GaN material properties and the growth conditions of radio frequency plasma-assisted molecular beam epitaxy [J].
Amimer, K ;
Georgakilas, A ;
Androulidaki, M ;
Tsagaraki, K ;
Pavelescu, M ;
Mikroulis, S ;
Constantinidis, G ;
Arbiol, J ;
Peiro, F ;
Cornet, A ;
Calamiotou, M ;
Kuzmik, J ;
Davydov, VY .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2001, 80 (1-3) :304-308
[2]   Energetics of AlN thin films on the Al2O3(0001) surface [J].
Di Felice, R ;
Northrup, JE .
APPLIED PHYSICS LETTERS, 1998, 73 (07) :936-938
[3]  
Georgakilas A, 2001, PHYS STATUS SOLIDI A, V188, P567, DOI 10.1002/1521-396X(200112)188:2<567::AID-PSSA567>3.0.CO
[4]  
2-W
[5]   Nitridation of sapphire. Effect on the optical properties of GaN epitaxial overlayers [J].
Grandjean, N ;
Massies, J ;
Leroux, M .
APPLIED PHYSICS LETTERS, 1996, 69 (14) :2071-2073
[6]   Preconditioning of c-plane sapphire for GaN epitaxy by radio frequency plasma nitridation [J].
Heinlein, C ;
Grepstad, J ;
Berge, T ;
Riechert, H .
APPLIED PHYSICS LETTERS, 1997, 71 (03) :341-343
[7]  
Heinlein C, 1999, MAT SCI ENG B-SOLID, V58, P270
[8]   GROWTH OF GAN BY ECR-ASSISTED MBE [J].
MOUSTAKAS, TD ;
LEI, T ;
MOLNAR, RJ .
PHYSICA B, 1993, 185 (1-4) :36-49
[9]   Molecular beam epitaxial growth of normal and inverted two-dimensional electron gases in AlGaN GaN based heterostructures [J].
Murphy, MJ ;
Chu, K ;
Wu, H ;
Yeo, W ;
Schaff, WJ ;
Ambacher, O ;
Smart, J ;
Shealy, JR ;
Eastman, LF ;
Eustis, TJ .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1999, 17 (03) :1252-1254
[10]   Determination of wurtzite GaN lattice polarity based on surface reconstruction [J].
Smith, AR ;
Feenstra, RM ;
Greve, DW ;
Shin, MS ;
Skowronski, M ;
Neugebauer, J ;
Northrup, JE .
APPLIED PHYSICS LETTERS, 1998, 72 (17) :2114-2116