Copper-in-charcoal (Cu/C): Heterogeneous, copper-catalyzed asymmetric hydrosilylations

被引：99

作者：

Lipshutz, BH ^{[1
]}

Frieman, BA ^{[1
]}

Tomaso, AE ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 08期

关键词：

asymmetric catalysis; copper; heterogeneous catalysis; hydrosilylation;

D O I：

10.1002/anie.200503149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric copper chemistry ... done heterogeneously? It's doable: Copper-incharcoal (Cu/C) is introduced as an easily prepared catalyst that is readily converted in situ into a nonracemically ligated form of copper hydride that effects asymmetric hydrosilylations. DTBM = 3,5-di-tert-butyl-4- methoxydiphenylphosphinyl. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1259 / 1264

页数：6

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