Asymmetric π-allylic etherification of cycloalkenyl esters with phenols in water using a resin-supported chiral palladium complex

被引：64

作者：

Uozumi, Y ^{[1
]}

Kimura, M ^{[1
]}

机构：

[1] Grad Univ Adv Studies, CREST, Inst Mol Sci, Okazaki, Aichi 4448787, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 01期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

D O I：

10.1016/j.tetasy.2005.11.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Catalytic asymmetric etherification of cycloalkenyl esters with phenolic nucleophiles was achieved in water as the sole reaction medium under heterogeneous conditions by using 2 mol % palladium of a PS-PEG resin-supported palladium-imidazo-indolephosphine complex to give optically active aryi(cycloalkenyl) ethers with up to 94% ee. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：161 / 166

页数：6

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