Significant zirconium-alkyl group effects an ion pair formation thermodynamics and structural reorganization dynamics in zirconocenium alkyls

被引：67

作者：

Beswick, CL ^{[1
]}

Marks, TJ ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 13期

关键词：

D O I：

10.1021/om990274z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Substantial Zr-alkyl group (R) effects on ion pair thermodynamic stability as well as on ion pair solution structure and structural dynamics are reported in the [(1,2-Me2Cp)(2)ZrR](+)[CH3B(C6F5)(3)](-) series, where R = CH3, CH2C(CH3)(3), CH2Si(CH3)(3), and CH[Si(CH3)(3)](2). These quantitative results underscore the effects such R moieties are likely to play in group 4 metallocene-mediated olefin polymerization catalysis.

引用

页码：2410 / 2412

页数：3

共 42 条

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