Hydrogen bond dynamics at vapour-water and metal-water interfaces

被引：103

作者：

Paul, S ^{[1
]}

Chandra, A ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 386卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2003.12.120

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have presented a molecular dynamics study of the dynamics of breaking and structural relaxation of hydrogen bonds at vapour-water and metal-water interfaces. For both interfaces, the relaxation of hydrogen bonds is found to occur at a slower rate than that in bulk water. However, the dynamics of inter-region hydrogen bonds, where one molecule of the bonded pair belongs to interface and the other to its adjacent layer, are found to be faster than even the bulk hydrogen bonds. The results are explained in terms of the energies of hydrogen bonds and the frictions that act on the rotational and translational motion of water molecules at interfaces. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：218 / 224

页数：7

共 36 条

[21] HYDROGEN-BONDS IN WATER NETWORK ORGANIZATION AND LIFETIMES [J].

RAPAPORT, DC .

MOLECULAR PHYSICS, 1983, 50 (05) :1151-1162

[22] Hydrogen-bonding interactions at the vapor/water interface investigated by vibrational sum-frequency spectroscopy of HOD/H2O/D2O mixtures and molecular dynamics simulations [J].

Raymond, EA ;

Tarbuck, TL ;

Brown, MG ;

Richmond, GL .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (02) :546-556

[23] Water at hydrophobic surfaces: Weak hydrogen bonding and strong orientation effects [J].

Scatena, LF ;

Brown, MG ;

Richmond, GL .

SCIENCE, 2001, 292 (5518) :908-912

[24] Modeling and structure of mercury-water interfaces [J].

Shelley, JC ;

Patey, GN ;

Berard, DR ;

Torrie, GM .

JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (06) :2122-2141

[25] The free surface of water: molecular orientation, surface potential and nonlinear susceptibility [J].

Sokhan, VP ;

Tildesley, DJ .

MOLECULAR PHYSICS, 1997, 92 (04) :625-640

[26] Fast and slow dynamics of hydrogen bonds in liquid water [J].

Starr, FW ;

Nielsen, JK ;

Stanley, HE .

PHYSICAL REVIEW LETTERS, 1999, 82 (11) :2294-2297

[27]

Tarek M, 2002, Phys Rev Lett, V88, P138101

[28] Molecular dynamics simulations of the liquid/vapor interface of SPC/E water [J].

Taylor, RS ;

Dang, LX ;

Garrett, BC .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (28) :11720-11725

[29] VOLTAGE-DEPENDENT ORDERING OF WATER-MOLECULES AT AN ELECTRODE-ELECTROLYTE INTERFACE [J].

TONEY, MF ;

HOWARD, JN ;

RICHER, J ;

BORGES, GL ;

GORDON, JG ;

MELROY, OR ;

WIESLER, DG ;

YEE, D ;

SORENSEN, LB .

NATURE, 1994, 368 (6470) :444-446

[30] Solvation dynamics at the interface between water and self-assembled monolayers [J].

Vieceli, J ;

Benjamin, I .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (20) :4801-4810

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