Highly reversible lithium storage in Si (core)-hollow carbon nanofibers (sheath) nanocomposites

被引：58

作者：

Wang, Jiaqing ^{[1
]}

Yu, Yan ^{[1
]}

Gu, Lin ^{[2
]}

Wang, Chunlei ^{[3
]}

Tang, Kun ^{[4
]}

Maier, Joachim ^{[4
]}

机构：

[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China

[2] Chinese Acad Sci, Beijing Lab Electron Microscopy, Inst Phys, Beijing 100190, Peoples R China

[3] Florida Int Univ, Dept Mech & Mat Engn, Miami, FL 33174 USA

[4] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

来源：

NANOSCALE | 2013年 / 5卷 / 07期

关键词：

LI-ION BATTERIES; ANODE MATERIAL; ELECTROCHEMICAL PROPERTIES; SILICON; PERFORMANCE; CAPACITY; ELECTRODE; COMPOSITES; EXTRACTION; INSERTION;

D O I：

10.1039/c3nr00322a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A favorable Si (core)-hollow carbon nanofiber (sheath) nanocomposite, was synthesized by a coaxial electrospinning technique. As a potential anode material for LIBs, this composite displays a high reversible capacity of 1300 mA h g(-1) even after 80 cycles at 0.5 C. It also exhibits a reversible discharge capacity as high as 700 mA h g(-1) when cycled at 3 C. This makes the Si-C composite a promising candidate for use as an anode material in lithium ion batteries. Beyond that, coaxial electrospinning has proved itself as a powerful technique to prepare nanomaterials with hollow core-shell architectures.

引用

页码：2647 / 2650

页数：4

共 33 条

[1] Silicon and carbon based composite anodes for lithium ion batteries [J].

Datta, Moni Kanchan ;

Kumta, Prashant N. .

JOURNAL OF POWER SOURCES, 2006, 158 (01) :557-563

[2] Carbon-coated silicon as anode material for lithium ion batteries: advantages and limitations [J].

Dimov, N ;

Kugino, S ;

Yoshio, M .

ELECTROCHIMICA ACTA, 2003, 48 (11) :1579-1587

[3] Structured silicon anodes for lithium battery applications [J].

Green, M ;

Fielder, E ;

Scrosati, B ;

Wachtler, M ;

Serra Moreno, J .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (05) :A75-A79

[4] In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix [J].

Gu, Meng ;

Li, Ying ;

Li, Xiaolin ;

Hu, Shenyang ;

Zhang, Xiangwu ;

Xu, Wu ;

Thevuthasan, Suntharampillai ;

Baer, Donald R. ;

Zhang, Ji-Guang ;

Liu, Jun ;

Wang, Chongmin .

ACS NANO, 2012, 6 (09) :8439-8447

[5] Chemical vapor deposited silicon/graphite compound material as negative electrode for lithium-ion batteries [J].

Holzapfel, M ;

Buqa, H ;

Krumeich, F ;

Novák, P ;

Petrat, FM ;

Veit, C .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (10) :A516-A520

[6] A new type of nano-sized silicon/carbon composite electrode for reversible lithium insertion [J].

Holzapfel, M ;

Buqa, H ;

Scheifele, W ;

Novák, P ;

Petrat, FM .

CHEMICAL COMMUNICATIONS, 2005, (12) :1566-1568

[7] Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries [J].

Hu, Yong-Sheng ;

Demir-Cakan, Rezan ;

Titirici, Maria-Magdalena ;

Mueller, Jens-Oliver ;

Schloegl, Robert ;

Antonietti, Markus ;

Maier, Joachim .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (09) :1645-1649

[8] Cyclic properties of Si-Cu/carbon nanocomposite anodes for Li-ion secondary batteries [J].

Kim, BC ;

Uono, H ;

Satou, T ;

Fuse, T ;

Ishihara, T ;

Ue, M ;

Senna, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (03) :A523-A526

[9] Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries [J].

Kim, Hyunjung ;

Han, Byunghee ;

Choo, Jaebum ;

Cho, Jaephil .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (52) :10151-10154

[10]

Kim I, 2000, ELECTROCHEM SOLID ST, V3, P493

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