Highly reversible lithium storage in Si (core)-hollow carbon nanofibers (sheath) nanocomposites

被引:59
作者
Wang, Jiaqing [1 ]
Yu, Yan [1 ]
Gu, Lin [2 ]
Wang, Chunlei [3 ]
Tang, Kun [4 ]
Maier, Joachim [4 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China
[2] Chinese Acad Sci, Beijing Lab Electron Microscopy, Inst Phys, Beijing 100190, Peoples R China
[3] Florida Int Univ, Dept Mech & Mat Engn, Miami, FL 33174 USA
[4] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
关键词
LI-ION BATTERIES; ANODE MATERIAL; ELECTROCHEMICAL PROPERTIES; SILICON; PERFORMANCE; CAPACITY; ELECTRODE; COMPOSITES; EXTRACTION; INSERTION;
D O I
10.1039/c3nr00322a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A favorable Si (core)-hollow carbon nanofiber (sheath) nanocomposite, was synthesized by a coaxial electrospinning technique. As a potential anode material for LIBs, this composite displays a high reversible capacity of 1300 mA h g(-1) even after 80 cycles at 0.5 C. It also exhibits a reversible discharge capacity as high as 700 mA h g(-1) when cycled at 3 C. This makes the Si-C composite a promising candidate for use as an anode material in lithium ion batteries. Beyond that, coaxial electrospinning has proved itself as a powerful technique to prepare nanomaterials with hollow core-shell architectures.
引用
收藏
页码:2647 / 2650
页数:4
相关论文
共 33 条
[31]   Preparation and electrochemical properties of core-shell Si/SiO nanocomposite as anode material for lithium ion batteries [J].
Zhang, T. ;
Gao, J. ;
Zhang, H. P. ;
Yang, L. C. ;
Wu, Y. P. ;
Wu, H. Q. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (05) :886-890
[32]   Electrochemical performance of lithium ion battery, nano-silicon-based, disordered carbon composite anodes with different microstructures [J].
Zhang, XW ;
Patil, PK ;
Wang, CS ;
Appleby, AJ ;
Little, FE ;
Cocke, DL .
JOURNAL OF POWER SOURCES, 2004, 125 (02) :206-213
[33]   Electrospun polyacrylonitrile/poly (methyl methacrylate)-derived turbostratic carbon micro-/nanotubes [J].
Zussman, E ;
Yarin, AL ;
Bazilevsky, AV ;
Avrahami, R ;
Feldman, M .
ADVANCED MATERIALS, 2006, 18 (03) :348-+