1D, nano-dimensional pore and square grid metal-organic polymers based on 4,4′-oxybisbenzoate; synthesis, characterization, and thermal properties

被引:5
作者
Xiao, Hong-Ping [1 ]
Aghabeygi, Shokufeh [2 ]
Wang, Si-Si [1 ]
Wu, Hong-Ya [1 ]
Tong, Chao-Er [1 ]
Zhang, Wei-Bing [1 ]
Morsali, Ali [3 ]
机构
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou, Peoples R China
[2] Islamic Azad Univ, Dept Chem, East Tehran Branch, Tehran, Iran
[3] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran
关键词
Nano-dimensional square grid; Zinc(II); Coordination polymer; 4; 4-Oxybis(benzoic acid); COORDINATION POLYMERS; BIS(IMIDAZOLE) LIGANDS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; COMPLEXES; ACID; COBALT(II); FRAMEWORK; ZINC(II); ACETATE;
D O I
10.1080/00958972.2013.790965
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three new zinc(II) coordination polymers, [Zn(imi)(2)(-oba)] (n)center dot nH(2)O (1), [Zn(2,2-bipy)(-oba)(H2O)] (n)center dot nH(2)O (2), and [Zn-2(4,4-bipy)(-oba)(2)(H2O)(2)(DMF)(2)] (n)center dot nDMF (3) (oba=4,4 '-oxybisbenzoate, imi=imidazole), have been synthesized and structurally characterized by single-crystal X-ray crystallography and FT-IR spectroscopy. The coordination polymers 1-3 have 1D, nano-dimensional pore and square grid structures. The thermal stabilities of 1-3 were studied by thermal gravimetric and differential thermal analysis.
引用
收藏
页码:1821 / 1829
页数:9
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