Steps toward the synthesis of a geodesic C60H12 end cap for a C3v carbon [6,6]nanotube

被引：44

作者：

Hill, Thomas J. ^{[1
]}

Hughes, Richard K. ^{[1
]}

Scott, Lawrence T. ^{[1
]}

机构：

[1] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

TETRAHEDRON | 2008年 / 64卷 / 50期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.tet.2008.09.087

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several shape-persistent carbon-rich nanomolecules with diameters exceeding 1.7 nm have been prepared by the aldol trimerization of 20-carbon aromatic ketones bearing chlorine atoms at Various sites. These C60H27Cl3 and C60H24Cl6 polycyclic aromatic compounds represent attractive intermediates for the synthesis of a geodesic C60H12 end cap of a C-3v carbon [6,6]nanotube. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：11360 / 11369

页数：10