Mechanistic Investigations of the Iridium(III)-Catalyzed Aerobic Oxidation of Primary and Secondary Alcohols

被引：74

作者：

Jiang, Bi ^{[1
]}

Feng, Yuee ^{[1
]}

Ison, Elon A. ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 44期

关键词：

D O I：

10.1021/ja8049595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The commercially available catalysts [(Cp*IrCl2)(2)] is employed with O-2 as the terminal oxidant in the presence of catalytic amounts of Et3N for the aerobic oxidation of primary and secondary alcohols. A new mechanism for the Ir-catalyzed aerobic oxidation is also presented that suggests that the transition metal maintains its +3 oxidation state throughout the entire catalytic cycle.

引用

页码：14462 / +

页数：4

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