Ruthenium complex catalyzed direct ortho arylation and alkenylation of aromatic Imines with organic halides

被引：182

作者：

Oi, S ^{[1
]}

Ogino, Y ^{[1
]}

Fukita, S ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Sendai, Miyagi 9808579, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 10期

关键词：

D O I：

10.1021/ol025851l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The ortho position of the aromatic ring of imino group substituted aromatic compounds is directly arylated and alkenylated with organic halides in the presence of a catalytic amount of a ruthenium(II)-phosphine complex.

引用

页码：1783 / 1785

页数：3

共 26 条

[1] Palladium-catalyzed tert-butoxycarbonylation of trifluoroacetimidoyl iodides [J].

Amii, H ;

Kishikawa, Y ;

Kageyama, K ;

Uneyama, K .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (11) :3404-3408

[2] Asymmetric synthesis of α-arylglycinols via additions of lithium methyl p-tolyl sulfoxide to N-(PMP)arylaldimines followed by "non oxidative" Pummerer reaction [J].

Bravo, P ;

Capelli, S ;

Crucianelli, M ;

Guidetti, M ;

Markovsky, AL ;

Meille, SV ;

Soloshonok, VA ;

Sorochinsky, AE ;

Viani, F ;

Zanda, M .

TETRAHEDRON, 1999, 55 (10) :3025-3040

[3]

Dyker G, 1999, ANGEW CHEM INT EDIT, V38, P1699, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1698::AID-ANIE1698>3.0.CO

[4]

2-6

[5]

FUJIWARA Y, 1990, CHEMTECH, V20, P636

[6] PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF ORGANOMETALLOIDS THROUGH ACTIVATION WITH FLUORIDE-ION [J].

HIYAMA, T ;

HATANAKA, Y .

PURE AND APPLIED CHEMISTRY, 1994, 66 (07) :1471-1478

[7]

Kakiuchi F, 2001, SYNLETT, P948

[8] Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins [J].

Kakiuchi, F ;

Yamauchi, M ;

Chatani, N ;

Murai, S .

CHEMISTRY LETTERS, 1996, (02) :111-112

[9] New protocol for the site-selective alkylation and vinylation of aromatic compounds. Catalyst-specific reactions [J].

Kakiuchi, F ;

Sato, T ;

Tsujimoto, T ;

Yamauchi, M ;

Chatani, N ;

Murai, S .

CHEMISTRY LETTERS, 1998, (10) :1053-1054

[10] Regioselective arylation of benzanilides with aryl triflates or bromides under palladium catalysis [J].

Kametani, Y ;

Satoh, T ;

Miura, M ;

Nomura, M .

TETRAHEDRON LETTERS, 2000, 41 (15) :2655-2658

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