A Water-Stable Porphyrin-Based Metal-Organic Framework Active for Visible-Light Photocatalysis

被引：708

作者：

Fateeva, Alexandra ^{[1
]}

Chater, Philip A. ^{[1
]}

Ireland, Christopher P. ^{[1
]}

Tahir, Asif A. ^{[1
]}

Khimyak, Yaroslav Z. ^{[1
]}

Wiper, Paul V. ^{[1
]}

Darwent, James R. ^{[1
]}

Rosseinsky, Matthew J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L697ZD, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 30期

基金：

英国工程与自然科学研究理事会;

关键词：

heterogeneous catalysis; hydrogen production; metal-organic frameworks; porphyrinoids; CARBON-DIOXIDE; COORDINATION POLYMERS; IRON(III) PORPHYRINS; ALUMINUM PORPHYRIN; HYDROGEN; METALLOPORPHYRINS; REDUCTION; TOPOLOGY; NETWORK; SERIES;

D O I：

10.1002/anie.201202471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7440 / 7444

页数：5

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