Ammonia borane destabilized by lithium hydride: An advanced on-board hydrogen storage material

被引：168

作者：

Kang, Xiangdong ^{[1
]}

Fang, Zhanzhao ^{[1
]}

Kong, Lingyan ^{[1
]}

Cheng, Huiming ^{[1
]}

Yao, Xiangdong ^{[2
]}

Lu, Gaoqing ^{[2
]}

Wang, Ping ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China

[2] Univ Queensland, ARC Ctr Funct Nanomat, Brisbane, Qld 4072, Australia

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 14期

关键词：

D O I：

10.1002/adma.200702958

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An advanced hydrogen storage material with potential for on-board application, is readily prepared by mechanically milling a 1:1 ammonia borane/lithium hydride (AB/LiH) mixture. The material possesses a H capacity of around 10 wt %, higher than the 2015 DOE gravimetric H capacity target, and can rapidly release over 7 wt % pure H-2 at around 100 degrees C.

引用

页码：2756 / +

页数：5

共 29 条

[11] Decomposition kinetics of the AlH3 polymorphs [J].

Graetz, J ;

Reilly, JJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (47) :22181-22185

[12] Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen [J].

Grochala, W ;

Edwards, PP .

CHEMICAL REVIEWS, 2004, 104 (03) :1283-1315

[13] Nanoscaffold mediates hydrogen release and the reactivity of ammonia borane [J].

Gutowska, A ;

Li, LY ;

Shin, YS ;

Wang, CMM ;

Li, XHS ;

Linehan, JC ;

Smith, RS ;

Kay, BD ;

Schmid, B ;

Shaw, W ;

Gutowski, M ;

Autrey, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) :3578-3582

[14] NEW SYNTHETIC APPROACHES TO AMMONIA-BORANE AND ITS DEUTERATED DERIVATIVES [J].

HU, MG ;

VANPAASSCHEN, JM ;

GEANANGEL, RA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (12) :2147-2150

[15] THERMAL-DECOMPOSITION OF AMMONIA-BORANE [J].

HU, MG ;

GEANANGEL, RA ;

WENDLANDT, WW .

THERMOCHIMICA ACTA, 1978, 23 (02) :249-255

[16]

*HYDR FUEL CELLS I, 2007, MULT RES DEV DEM PLA

[17] Base metal catalyzed dehydrogenation of ammonia-borane for chemical hydrogen storage [J].

Keaton, Richard J. ;

Blacquiere, Johanna M. ;

Baker, R. Tom .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) :1844-+

[18]

MARDER BT, 2007, ANGEW CHEM INT EDIT, V46, P2

[19]

MAYERS AG, 1996, TETRAHEDRON LETT, V37, P3623

[20]

MOHAJERI N, 2006, PREP S ACS DIV FUEL, V51, P520

← 1 2 3 →