Hypergolic Ionic Liquids with the 2,2-Dialkyltriazanium Cation

被引：121

作者：

Gao, Haixiang ^{[1
]}

Joo, Young-Hyuk ^{[2
]}

Twamley, Brendan ^{[2
]}

Zhou, Zhiqiang ^{[1
]}

Shreeve, Jean'ne M. ^{[2
]}

机构：

[1] China Agr Univ, Dept Appl Chem, Beijing 100193, Peoples R China

[2] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 15期

关键词：

hypergolic propellants; ignition delay; ionic liquids; propellants; sustainable chemistry; SALTS; DERIVATIVES; CHEMISTRY; HYDRAZINE; CRYSTAL;

D O I：

10.1002/anie.200900094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No flame, no gain: A hypergolic mixture is composed of stable species that readily react/ignite on molecular contact. Both the anion and the cation in an ionic liquid play prominent roles in determining hypergolic properties as well as ignition delay times. With the 2,2-dialkyltriazanium cation, salts with nitrate, chloride, nitrocyanamide, and dicyanamide anions are hypergolic. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2792 / 2795

页数：4

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