A new carbonate bridged dinuclear zinc complex with tripodal amine ligands

被引：35

作者：

Dietrich, J ^{[1
]}

Heinemann, FW ^{[1
]}

Schrodt, A ^{[1
]}

Schindler, S ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany

来源：

INORGANICA CHIMICA ACTA | 1999年 / 288卷 / 02期

关键词：

crystal structures; zinc complexes; tripodal amine complexes; carbonate complexes;

D O I：

10.1016/S0020-1693(99)00093-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A zinc complex with the tripodal ligand bis[2-(2-pyridyl)ethyl]-(2-pyridyl)methylamine (pmap) reacts with carbon dioxide to form a new dinuclear carbonate bridged zinc complex, [mu-CO3 {Zn(pmap)}(2)](ClO4)(2). This complex was structurally characterized and shows a binding mode for carbonate, which so far has not been observed for zinc carbonate complexes. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：206 / 209

页数：4

共 21 条

[11]

Kimura E, 1997, STRUCT BOND, V89, P1

[12]

Kimura E., 1991, COMMENTS INORG CHEM, V11, P285

[13] FIXATION OF ATMOSPHERIC CO2 BY A SERIES OF HYDROXO COMPLEXES OF DIVALENT METAL-IONS AND THE IMPLICATION FOR THE CATALYTIC ROLE OF METAL-ION IN CARBONIC-ANHYDRASE - SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF [LM(OH)]N (N = 1 OR 2) AND LM(MU-CO3)ML (M(II) = MN, FE, CO, NI, CU, ZN L = HB(3,5-IPR2PZ)3) [J].

KITAJIMA, N ;

HIKICHI, S ;

TANAKA, M ;

MOROOKA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) :5496-5508

[14] SYNTHESIS AND CHARACTERIZATION OF THE DINUCLEAR COPPER(II) COMPLEXES [CU(HB(3,5-ME2PZ)3)]2X (X = O2-, (OH)2(2-), CO3(2-), O2(2-)) [J].

KITAJIMA, N ;

KODA, T ;

HASHIMOTO, S ;

KITAGAWA, T ;

MOROOKA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) :5664-5671

[15]

Looney A., 1992, ANGEW CHEM, V104, P57

[16] A DINUCLEAR ZINC HYDROXIDE COMPLEX WHICH TRAPS ATMOSPHERIC CARBON-DIOXIDE - FORMATION OF A TRI-ZINC COMPLEX WITH A TRIPLY BRIDGING CARBONATE GROUP [J].

MURTHY, NN ;

KARLIN, KD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (15) :1236-1238

[17]

RHEINGOLD AL, 1994, ANGEW CHEM, V106, P2053

[18]

*SIEM AN XRAY INST, 1995, SHELXTL 5 03

[19] PHASE-TRANSITION AND EXCHANGE INTERACTION IN (MU-CARBONATO)BIS[(N,N,N',N'',N''-PENTAETHYLDIETHYLENETRIAMINE)COPPER(II)] DIPERCHLORATE [J].

SLETTEN, J ;

HOPE, H ;

JULVE, M ;

KAHN, O ;

VERDAGUER, M ;

DWORKIN, A .

INORGANIC CHEMISTRY, 1988, 27 (03) :542-549

[20] STERICALLY HINDERED [TRIS(IMIDAZOLYL)PHOSPHINE]COPPER COMPLEXES - FORMATION AND REACTIVITY OF A PEROXO-DICOPPER(II) ADDUCT AND STRUCTURE OF A DINUCLEAR CARBONATE-BRIDGED COMPLEX [J].

SORRELL, TN ;

ALLEN, WE ;

WHITE, PS .

INORGANIC CHEMISTRY, 1995, 34 (04) :952-960

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