Development of the dipole moment and polarizability operators of octahedral molecules

被引：53

作者：

Cheblal, N ^{[1
]}

Loëte, M ^{[1
]}

Boudon, V ^{[1
]}

机构：

[1] Univ Bourgogne, CNRS, Phys Lab, F-21078 Dijon, France

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1999年 / 197卷 / 02期

关键词：

D O I：

10.1006/jmsp.1999.7902

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We present a development of the dipole moment and polarizability operators of octahedral molecules, using a tensorial formalism analogous to the one developed for tetrahedral molecules. These operators are involved in the calculation of the intensities of rovibrational transitions as well as in the calculation of the Stark effect. Expressions for the matrix elements are derived. Two simplified models for the study of the Stark effect in such molecules are also proposed and discussed. (C) 1999 Academic Press.

引用

页码：222 / 231

页数：10

共 24 条

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ACEF MO, IN PRESS

[2] SIDE-BAND DOUBLE-MODULATION - THE GROUND-STATE DIPOLE-MOMENT OF SIF4 [J].