The structural evolution of nanocrystalline diamond films synthesized by r.f. PECVD
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作者:
Liang, XB
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Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
Liang, XB
[1
]
Wang, L
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Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
Wang, L
[1
]
Yang, DR
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Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
Yang, DR
[1
]
机构:
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
Nanocrystalline diamond films (NDFs) have been deposited using radio-frequency plasma enhanced chemical vapor deposition (r.f-PECVD) at temperature as low as 500 degrees C. The CO/H-2 ratio has been shown to exert a profound effect on the structure configuration of the NDFs. The nanoscale structures of the films have been shown to evolve from columnar structure to grainy structure with the increase of the CO/H-2 ratio from 12:1 to 20:1. Such evolution is suggested to be the result of the enhanced secondary nucleation process. It gives an insight of the nucleation and growth process of NDFs and provides useful information on the optimal control of NDFs deposition. (c) 2005 Elsevier B.V. All rights reserved.
机构:
Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, IndiaBhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
Dua, AK
;
George, VC
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机构:Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
George, VC
;
Friedrich, M
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机构:Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
Friedrich, M
;
Zahn, DRT
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机构:Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
机构:
Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, IndiaBhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
Dua, AK
;
George, VC
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机构:Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
George, VC
;
Friedrich, M
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机构:Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
Friedrich, M
;
Zahn, DRT
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机构:Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India