A new advanced lithium ion battery: Combination of high performance amorphous columnar silicon thin film anode, 5 V LiNi0.5Mn1.5O4 spinel cathode and fluoroethylene carbonate-based electrolyte solution

被引:81
作者
Fridman, K. [1 ]
Sharabi, R. [1 ]
Elazari, R. [1 ]
Gershinsky, G. [1 ]
Markevich, E. [1 ]
Salitra, G. [1 ]
Aurbach, D. [1 ]
Garsuch, A. [2 ]
Lampert, J. [2 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] BASF SE, D-67056 Ludwigshafen, Germany
关键词
Silicon anode; LiNi0; 5Mn1.5O4; 5 V lithium-ion battery; Fluoroethylene carbonate; FORMING ADDITIVES; COMPOSITE; LIFE;
D O I
10.1016/j.elecom.2013.04.010
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A new advanced Li-ion battery comprising a high performance amorphous columnar silicon thin film anode, a high voltage LiNi0.5Mn1.5O4 spinel composite cathode and fluoroethylene carbonate (FEC)-based electrolyte solution (FEC/DMC 1:4 with 1 M LiPF6) is reported. This advanced battery demonstrated hundreds of cycles, excellent charge-discharge efficiency and rate capability. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:31 / 34
页数:4
相关论文
共 16 条
[1]   TiO2(B) nanowires as an improved anode material for lithium-ion batteries containing LiFePO4 or LiNi0.5Mn1.5O4 cathodes and a polymer electrolyte [J].
Armstrong, Graham ;
Armstrong, A. Robert ;
Bruce, Peter G. ;
Reale, Priscilla ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2006, 18 (19) :2597-+
[2]   Combining 5 V LiNi0.5Mn1.5O4 spinel and Si nanoparticles for advanced Li-ion batteries [J].
Arrebola, J. C. ;
Caballero, A. ;
Gomez-Camer, J. L. ;
Hernan, L. ;
Morales, J. ;
Sanchez, L. .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (05) :1061-1064
[3]   Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode [J].
Choi, Nam-Soon ;
Yew, Kyoung Han ;
Lee, Kyu Youl ;
Sung, Minseok ;
Kim, Ho ;
Kim, Sung-Soo .
JOURNAL OF POWER SOURCES, 2006, 161 (02) :1254-1259
[4]   Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].
Derrien, Gaelle ;
Hassoun, Jusef ;
Panero, Stefania ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2007, 19 (17) :2336-+
[5]   Li Ion Cells Comprising Lithiated Columnar Silicon Film Anodes, TiS2 Cathodes and Fluoroethyene Carbonate (FEC) as a Critically Important Component [J].
Elazari, Ran ;
Salitra, Gregory ;
Gershinsky, Gregory ;
Garsuch, Arnd ;
Panchenko, Alexander ;
Aurbach, Doron .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (09) :A1440-A1445
[6]   Rechargeable lithiated silicon-sulfur (SLS) battery prototypes [J].
Elazari, Ran ;
Salitra, Gregory ;
Gershinsky, Gregory ;
Garsuch, Arnd ;
Panchenko, Alexander ;
Aurbach, Doron .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 14 (01) :21-24
[7]   A New, Safe, High-Rate and High-Energy Polymer Lithium-Ion Battery [J].
Hassoun, Jusef ;
Panero, Stefania ;
Reale, Priscilla ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2009, 21 (47) :4807-+
[8]   In situ XRD and electrochemical study of the reaction of lithium with amorphous silicon [J].
Hatchard, TD ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (06) :A838-A842
[9]   Surface film formation on a graphite negative electrode in lithium-ion batteries: Atomic force microscopy study on the effects of film-forming additives in propylene carbonate solutions [J].
Jeong, SK ;
Inaba, M ;
Mogi, R ;
Iriyama, Y ;
Abe, T ;
Ogumi, Z .
LANGMUIR, 2001, 17 (26) :8281-8286
[10]   A high-rate long-life Li4Ti5O12/Li[Ni0.45Co0.1Mn1.45]O4 lithium-ion battery [J].
Jung, Hun-Gi ;
Jang, Min Woo ;
Hassoun, Jusef ;
Sun, Yang-Kook ;
Scrosati, Bruno .
NATURE COMMUNICATIONS, 2011, 2