Frequency-dependent vibrational population relaxation time of the OH stretching mode in liquid water

被引：75

作者：

Gale, GM ^{[1
]}

Gallot, G ^{[1
]}

Lascoux, N ^{[1
]}

机构：

[1] Ecole Polytech, Opt Quant Lab, F-91128 Palaiseau, France

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 311卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(99)00820-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational population relaxation time has been measured across the inhomogeneously broadened OH stretching mode (nu(3)) Of a 0.5% solution of HDO in D2O. Relaxation times vary from 0.5 ps at low frequency (3270 cm(-1)) to 1.0 ps at high frequency (3600 cm(-1)). This variation is attributed to a V-V transfer mechanism between nu(3) and 2 nu(2). (C) 1999 Elsevier Science B.V. All nights reserved.

引用

页码：123 / 125

页数：3

共 9 条

[1]

DIRAISON M, 1996, CHEM PHYS LETT, V258, P48

[2]

FINZI J, 1977, J CHEM PHYS, V67, P4053, DOI 10.1063/1.435379

[3] Femtosecond dynamics of hydrogen bonds in liquid water: A real time study [J].

Gale, GM ;

Gallot, G ;

Hache, F ;

Lascoux, N ;

Bratos, S ;

Leicknam, JC .

PHYSICAL REVIEW LETTERS, 1999, 82 (05) :1068-1071

[4] Generation of intense highly coherent femtosecond pulses in the mid infrared [J].

Gale, GM ;

Gallot, G ;

Hache, F ;

Sander, R .

OPTICS LETTERS, 1997, 22 (16) :1253-1255

[5] Dynamics of local substructures in water observed by ultrafast infrared hole burning [J].

Laenen, R ;

Rauscher, C ;

Laubereau, A .

PHYSICAL REVIEW LETTERS, 1998, 80 (12) :2622-2625

[6]

Pimentel G. C., 1960, The Hydrogen Bond

[7] CALCULATION OF VIBRATIONAL RELAXATION TIMES IN GASES [J].

SCHWARTZ, RN ;

SLAWSKY, ZI ;

HERZFELD, KF .

JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (10) :1591-1599

[8] Anomalous temperature dependence of vibrational lifetimes in water and ice [J].

Woutersen, S ;

Emmerichs, U ;

Nienhuys, HK ;

Bakker, HJ .

PHYSICAL REVIEW LETTERS, 1998, 81 (05) :1106-1109

[9] Femtosecond mid-IR pump-probe spectroscopy of liquid water: Evidence for a two-component structure [J].

Woutersen, S ;

Emmerichs, U ;

Bakker, HJ .

SCIENCE, 1997, 278 (5338) :658-660

← 1 →