Palladium catalysed regioselective arylation of indoles, benzofuran and benzothiophene with aryldiazonium salts

被引：47

作者：

Biajoli, Andre F. P. ^{[1
]}

da Penha, Eduardo T. ^{[1
]}

Correia, Carlos R. D. ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, UNICAMP, BR-13084971 Campinas, SP, Brazil

来源：

RSC ADVANCES | 2012年 / 2卷 / 31期

关键词：

C-H ARYLATION; DIAZONIUM SALTS; ARYL DIAZONIUM; C-2; ARYLATION; CYCLIZATION;

D O I：

10.1039/c2ra22213b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryldiazonium tetrafluoroborates have been successfully employed in the direct and regioselective arylation of heteroaromatics such as indole, benzofuran and benzothiophene. The cationic aryl palladium intermediates derived from the aryldiazonium salts act as effective electrophiles in the process. These arylating reactions display operational simplicity and provide the arylated heterocycles regioselectively in moderate to excellent yields.

引用

页码：11930 / 11935

页数：6

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