Selective epoxidation of styrene to styrene oxide by TBHP using simple transition metal oxides (NiO, CoO or MoO3) as highly active environmentally-friendly catalyst

被引：145

作者：

Choudhary, Vasant R. ^{[1
]}

Jha, Rani ^{[1
]}

Jana, Prabhas ^{[1
]}

机构：

[1] Natl Chem Lab, Chem Engn & Proc Dev Div, Pune 411008, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 10卷 / 02期

关键词：

Epoxidation; Styrene; Styrene oxide; TBHP; NiO; CoO; MoO3;

D O I：

10.1016/j.catcom.2008.08.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Simple transition metal oxides, such as NiO, CoO or MoO3, etc. show high catalytic activity for the selective epoxidation of styrene to styrene oxide by TBHP. The order of choice for different transition metal oxides for epoxidation is NiO > CoO > MoO3 > Cr2O3 > Fe2O3 > ZnO >= U3O8 >> TiO2 >> MnO2. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：205 / 207

页数：3

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