Palladium(II)-catalyzed synthesis of polyamides (aramids) from aromatic dichlorides, diamines, and carbon monoxide

被引：17

作者：

Kim, JS ^{[1
]}

Sen, A ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 143卷 / 1-3期

关键词：

palladium complex; carbonylation; polyamides; aramids;

D O I：

10.1016/S1381-1169(98)00387-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel catalytic procedure for the synthesis of polyamides (aramids) from aryl dichlorides, aryl diamines, and carbon monoxide has been developed. Palladium complexes incorporating bulky ligands, such as dippp (dippp=1,3-bis(diisopropylphosphino)propane), are suitable catalysts for the reaction. Polyamides exhibiting inherent viscosity between 0.10 and 0.40 dl g(-1) were obtained. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：197 / 201

页数：5

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