Assembly of dendrimers with redox-active [{CpFe(μ3-CO)}4] clusters at the periphery and their application to oxo-anion and adenosine-5′-triphosphate sensing

被引:49
作者
Aranzaes, JR
Belin, C
Astruc, D [1 ]
机构
[1] Univ Bordeaux 1, CNRS, UMR 5802, LCOO,Nanosci & Catalysis Grp, F-33405 Talence, France
[2] Univ Bordeaux 1, CNRS, UMR 5803, LPCM, F-33405 Talence, France
关键词
anions; cluster compounds; dendrimers; iron; sensors;
D O I
10.1002/anie.200502291
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
9, 16, or 27 [CpFe(μ3-CO)]4 clusters contain the title assemblies (see picture). The one-electron oxidation Fe 4→Fe4+of all Fe4 units appears as a single reversible cyclic voltammetry wave and was used in solution and with dendrimer-modified electrodes for oxo-anion recognition. ATP2- is selectively recognized and better than H2PO4-. The larger the dendrimer, the easier is the re-use of the modified electrode sensor. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:132 / 136
页数:5
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