Formation and reactivity of organometallic alkane complexes

被引：55

作者：

Cowan, Alexander J. ^{[1
]}

George, Michael W. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 23-24期

基金：

英国工程与自然科学研究理事会;

关键词：

Alkane complexes; Sigma complexes; C-H activation; Time-resolved spectroscopy; Time-resolved infrared;

D O I：

10.1016/j.ccr.2008.05.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organometallic alkane complexes are highly reactive species that have been shown to be key intermediates in the C-H activation of alkanes by transition metal centres. Organometallic alkane complexes were first identified in low temperature matrices over 30 years ago and now sufficiently long-lived examples have been characterised by NMR spectroscopy. We provide a brief overview of the study of these key reactive intermediates and describe recent studies on the characterisation of organometallic alkane complexes and their related C-H activation using fast time-resolved infrared (TRIR) spectroscopy. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2504 / 2511

页数：8

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